Carboxymethyl Cellulose (CMC) from Oil Palm Empty Fruit Bunch (OPEFB) in the new solvent Dimethyl Sulfoxide (DMSO)/Tetrabutylammonium Fluoride (TBAF)

3rd International Conference on Science & Engineering in Mathematics, Chemistry and Physics 2015

数学;化学;物理学

Eliza, M.Y.^1 ; Shahruddin, M.^1 ; Noormaziah, J.^1 ; Rosli, W. D. Wan^2

Faculty of Mechanical and Manufacturing Engineering, Universiti Tun Hussein, Onn Malaysia, Johor

86400, Malaysia^1

School of Industrial Technology, Universiti Sains Malaysia, Pulau Pinang, Minden

11800, Malaysia^2

关键词: Carboxymethyl cellulose;    Carboxymethyl group;    Degree of substitution;    Dimethyl sulfoxide (DMSO);    Diverse applications;    Empty fruit bunches;    Mixture solution;    Oil palm empty fruit bunch (OPEFB);   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/622/1/012026/pdf
DOI  :  10.1088/1742-6596/622/1/012026

来源: IOP

【 摘 要 】

The surplus of Oil Palm is the most galore wastes in Malaysia because it produced about half of the world palm oil production, which contributes a major disposal problem Synthesis from an empty fruit bunch produced products such as Carboxymethyl Cellulose (CMC), could apply in diverse application such as for paper coating, food packaging and most recently, the potential as biomaterials has been revealed. In this study, CMC was prepared by firstly dissolved the bleached pulp from OPEFB in mixture solution of dimethyl sulfoxide(DMSO)/tetrabutylammonium fluoride (TBAF) without any prior chemical modification. It took only 30 minutes to fully dissolve at temperature 60°C before sodium hydroxide (NaOH) were added for activation and monochloroacetateas terrifying agent. The final product is appeared in white powder, which is then will be analyzedby FTIR analysis. FTIR results show peaks appeared at wavenumber between 1609 cm-1to 1614 cm-1proved the existence of carboxymethyl groups which substitute OH groups at anhydroglucose(AGU) unit. As a conclusion, mixture solution of DMSO/TBAF is the suitable solvent used for dissolved cellulose before modifying it into CMC with higher Degree of Substitution (DS). Furthermore, the dissolution of the OPEFB bleached pulp was easy, simple and at a faster rate without prior chemical modification at temperature as low as 60°C.