Preparation and characterization of Cu2ZnSnSe4 thin films grown from ZnSe and Cu2SnS3 precursors in a two stage process

21st Latin American Symposium on Solid State Physics

Moreno, R.^1 ; Leguizamon, A.^2 ; Hurtado, M.^1 ; Guzmán, F.^1 ; Gordillo, G.^1

Departamento de Física, Universidad Nacional de Colombia, Bogotá, Colombia^1

Universidad Libre, Bogotá, Colombia^2

关键词: Absorption co-efficient;    Electrical transport properties;    Environmental-friendly;    Optical characterization;    Spectral transmittance;    Temperature-dependent conductivity;    Two-stage process;    Type structures;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/480/1/012007/pdf
DOI  :  10.1088/1742-6596/480/1/012007

来源: IOP

【 摘 要 】

Compound of the kesterite familie has been considered as an alternative absorber layer in the manufacture of thin film solar cells due to its earth abundant and environmental friendly constituents and high absorption coefficient. In this work we propose a new route to grow single phase Cu2ZnSnSe4(CZTSe) thin films with tetragonal-kesterite type structure; this consist in sequential evaporation of thin films of CuSe, SnSe and ZnSe in a two stage process. Measurements of X-ray diffraction (XRD) revealed the formation of the Cu2ZnSnSe4compound, grown with tetragonal Kesterite type structure. Optical characterization performed through spectral transmittance measurements established that this compound has high absorption (absorption coefficient > 104cm-1) and a forbidden energy gap of 1.46 eV; these results indicate that the CZTSe thin films we have prepared has properties suitable for later use as absorber layer in solar cells. Results regarding electrical transport properties determined from temperature dependent conductivity measurements are also reported.