Synthesis and Crystal Structure of the Energetic Compound [BAP(NO3) (ClO4)]

2018 4th International Conference on Environmental Science and Material Application

生态环境科学;材料科学

Gao, Fulei^1 ; Liu, Weixiao^1 ; Pan, Yongfei^1 ; Chen, Bin^1 ; Wang, Yinglei^1

Xi'An Modern Chemistry Research Institute, Xi'an, China^1

关键词: Crystal parameters;    Crystallographic data;    Energetic compounds;    FTIR spectroscopy;    Slow evaporation;    Synthesis and crystal structure;    Triclinic space group;    X-ray single-crystal diffraction;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/252/2/022066/pdf
DOI  :  10.1088/1755-1315/252/2/022066

来源: IOP

【 摘 要 】

A novel azido amine compound of [BAP(NO3) (ClO4)] (BAP=N, N'-1,4-bis(2-azidoethyl)-piperazine) was synthesized for the first time. The structure of [BAP(NO3) (ClO4)] was characterized by elemental analysis and FT-IR spectroscopy. Single crystals of [BAP(NO3) (ClO4)] were obtained through slow evaporation of a saturated water solution. The crystal structure was determined by X-ray single crystal diffraction and the crystallographic data showed that the compound crystallizes in the triclinic space group P-1 with crystal parameters of a=6.4899(2) Å, b=11.2349(2) Å, c=12.1047(2) Å, α=105.524(2)°, β=91.065(2)°, γ=103.056(2)°, V=825.47(4) Å3, Z=2.