Synthesis and Characterization of Nickel, Palladium, Platinum and Cupper with New Oxazipine Ring

2nd International Scientific Conference (Pure Sciences, Brilliant Creativity and Renewed Building)

Abdulameer, Jihan Hameed^1 ; Abbas, Sawsan Khudhair^2 ; Mosa, Mosa Jaafar^3

Dep. of Chemistry, College of Education for Pure Sciences, University of Karbala, Karbala, Iraq^1

Dep. of Chemistry, College of Sciences, University of Karbala, Karbala, Iraq^2

Dep. of Nursing, Al-Safwa University College, Karbala, Iraq^3

关键词: As-ligands;    Cycloaddition reaction;    Oxazipine complexes;    Phthalic anhydrides;    Schiff-base;    Synthesis and characterizations;    Thiosemicarbazides;    Tridentate ligands;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/571/1/012099/pdf
DOI  :  10.1088/1757-899X/571/1/012099

来源: IOP

【 摘 要 】

Via cycloaddition reaction new seven membered Oxazipine ring was prepared by reaction of Schiff base with phthalic anhydride. Then we use the Oxazipine ring as ligand in this research and complexation with four transition metals Nickel, Palladium, Platinum and Cupper. Many techniques were used to identify the produced compound such as Melting Point, FT-IR, 1H NMR and UV-Vis. Finally and by evidences we conclude the geometry and hybridization of all prepared complexes.