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Bulletin of the Korean Chemical Society
Article

Colorimetric Detection of Hg2+ Based on Enhancement of Peroxidase‐like Activity of Chitosan‐Gold Nanoparticles

Cuifeng Jiang

Corresponding Author

E-mail address: cuifengj123@163.com

School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

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Zhuojian Li

School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

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Yinxing Wu

Materials Science and Chemical Engineering College, Anhui Jianzhu University, Hefei 230022, People's Republic of China

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Wei Guo

School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

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Jinshan Wang

School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

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Qiong Jiang

School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

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First published: 06 April 2018
Cited by: 3
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Abstract

Hg2+ is a serious environmental contaminant that can cause severe damage to the immune and nervous systems, and Hg2+ monitoring is critical. Herein, we report a novel, simple, and sensitive Hg2+ sensor based on the enhanced peroxidase‐like activity of chitosan–gold nanoparticles (CS‐AuNPs). The peroxidase‐like activity of the CS‐AuNPs can be markedly enhanced by Hg2+ as seen by the deeper color and increased absorbance at 652 nm. This improved catalytic ability was used to develop a sensitive and selective colorimetric sensor for Hg2+ detection. The limit of detection via the absorption spectra is as low as 0.02 μM. The mechanism underlying the enhanced catalytic ability is discussed. This approach is label‐free, simple, and offers detection with the naked eye. Thus, it has potential applications for the detection of Hg2+ in environmental and food samples.

Number of times cited according to CrossRef: 3

  • , Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes (II), Chemical Society Reviews, 10.1039/C8CS00457A, (2019).
  • , Preparation of [C 60 ]fullerene nanowhisker-silver nanoparticle composites and their catalytic activities for the oxidation of tetramethylbenzidine with hydrogen peroxide , Fullerenes, Nanotubes and Carbon Nanostructures, 10.1080/1536383X.2018.1511542, (1-5), (2018).
  • , Gold Nanoparticle-Based Colorimetric Strategies for Chemical and Biological Sensing Applications, Nanomaterials, 10.3390/nano9060861, 9, 6, (861), (2019).