Organic charge-transport materials based on oligothiophene and naphthalene diimide: towards ambipolar and air-stable n-channel organic field-effect transistors

Naphthalene diimide;Organic field-effect transistors;Organic electronics;Organic charge-transport materials

Polander, Lauren E. ; Chemistry and Biochemistry

University:Georgia Institute of Technology

Department:Chemistry and Biochemistry

关键词: Naphthalene diimide;    Organic field-effect transistors;    Organic electronics;    Organic charge-transport materials;   

Others  :  https://smartech.gatech.edu/bitstream/1853/45849/1/polander_lauren_e_201112_phd.pdf

美国|英语

来源: SMARTech Repository

【 摘 要 】

To better understand the physical and electronic properties of donor and acceptor-based structures used in organic electronic applications, a variety of oligothiophene and naphthalene diimide-based small conjugated molecules were designed, synthesized, and characterized. The materials were initially synthesized using oxidative copper-chloride coupling reactions, palladium-catalyzed amination reactions, Friedal-Crafts acylations, Negishi coupling reactions, and Stille coupling reactions. Once isolated, the physical properties of the compounds were characterized through a combination of X-ray crystal structure, thermogravimetric analysis, differential scanning calorimetry, UV-vis. absorption spectroscopy, cyclic voltammetry, and differential pulse voltammetry, along with comparison to quantum-chemical calculations. In some cases, the radical cations or radical anions were generated by chemical oxidation and analyzed by vis-NIR spectroscopy. Furthermore, the electronic properties of the materials were investigated through incorporation as solution-processed active layers in organic field-effect transistors. Multiple examples exhibited hole- and / or electron-transport properties with electron mobility values of up to 1.5 cm²V⁻¹s⁻¹, which is among the highest yet reported for an n-channel OFET based on a solution-processed small molecule.