Immobilization of organosilanes on support materials and their applications in CO2 capture and heterogeneous C–H functionalization catalysis

Organosilane;Immobilization;CO2 adsorption;Amine oxidation;C-H functionalization;Dirhodium catalyst;Cascade reaction

Yoo, Chunjae ; Jones, Christopher W. Chemical and Biomolecular Engineering Sievers, Carsten Lively, Ryan P. Boukouvala, Fani France, Stefan ; Jones, Christopher W.

University:Georgia Institute of Technology

Department:Chemical and Biomolecular Engineering

关键词: Organosilane;    Immobilization;    CO2 adsorption;    Amine oxidation;    C-H functionalization;    Dirhodium catalyst;    Cascade reaction;   

Others  :  https://smartech.gatech.edu/bitstream/1853/62225/1/YOO-DISSERTATION-2018.pdf

美国|英语

来源: SMARTech Repository

【 摘 要 】

In this dissertation, various organosilanes having multiple amine moieties are synthesized and utilized to understand the molecular mechanism for CO2 adsorption (fundamental aim), and immobilization method of dirhodium catalysts on silica support are explored to demonstrate C-H functionalization in flow reactor system (an applied goal)