Studies on the Pyrolysis of Chromated Copper Arsenate-Treated Wood: Analytical Methodology and Optimization

Low-temperature pyrolysis;CCA-treated wood;Levoglucosan;Levoglucosenone;31P NMR

Fu, Qirong ; Dimitris S. Argyropoulos, Committee Chair,Fu, Qirong ; Dimitris S. Argyropoulos ; Committee Chair

University:North Carolina State University

关键词: Low-temperature pyrolysis;    CCA-treated wood;    Levoglucosan;    Levoglucosenone;    31P NMR;   

Others  :  https://repository.lib.ncsu.edu/bitstream/handle/1840.16/5731/etd.pdf?sequence=1&isAllowed=y

美国|英语

来源: null

【 摘 要 】

Low temperature pyrolysis offers a feasible option for wood waste management and the recovery of a variety of useful chemicals. The effect of Chromated Copper Arsenate (CCA) wood preservatives on the yield and composition of various pyrolysis products was investigated in the present research. A novel quantitative 31P NMR methodology has been developed to quantify levoglucosan and levoglucosenone from the pyrolysate of CCA-treated and untreated wood. The CCA treatment on wood had a significant effect on the amount of main carbohydrate derived degradation products of tar. In particular, a higher yield of levoglucosan can be obtained compared to that from untreated wood. Phosphoric acid has proven to be an efficient catalyst to favor levoglucosenone formation. The pyrolysis of CCA-treated wood in the presence of phosphoric acid gave rise to high yields of levoglucosenone, which demonstrated the potential for a new pathway in the rational use of CCA-treated wood waste. Pretreated wood with metal compounds has demonstrated that K2Cr2O7 and CuSO4 salts promote the formation of levoglucosan. The CrO3 treatment was found to favor the formation of levoglucosenone. A kinetic study of the pyrolysis of CCA-treated wood by thermogravimetric analysis has shown that CCA components have a significant influence on the thermal decomposition behavior of CCA-treated wood, which accelerate the weight loss of wood and the oxidation of the char.