SO2 Gas Abatement Using Ionic Liquids for Marine Applications

Gas abatement;Ionic Liquids;Sulfur Dioxide

Patel, Pathikadvisor:Croiset, Eric ; advisor:Chen, Zhongwei ; affiliation1:Faculty of Engineering ; Croiset, Eric ; Chen, Zhongwei ;

University of Waterloo

关键词: Ionic Liquids;    Master Thesis;    Sulfur Dioxide;    Gas abatement;   

Others  :  https://uwspace.uwaterloo.ca/bitstream/10012/12908/3/Patel_Pathik.pdf

瑞士|英语

来源: UWSPACE Waterloo Institutional Repository

【 摘 要 】

Sulphur dioxide (SO2) emission has become one of the major challenging issues for cleanmarine transportation globally and especially in zero discharge zones Canada-wide with theimplementation of the International Maritime Organization (IMO) regulations. Currently, asper the IMO guidelines, zero-discharge scrubber technology is in use for the ships that operateon low cost high sulfur (3.5% w/w) heavy fuels. One of the main concerns with these scrubbertechnologies is the non-recyclability of the absorbent and high demand for onsite waste storagewhich takes a toll on process operating cost and cargo space.Owing to its high capacity, specific selectivity, recyclability, good thermodynamic propertiesand thermal stability, Ionic Liquids (ILs) can be used as an alternative solvent and need to betested to get measurable laboratory data. IMO regulations state that SO2 content release shouldbe within 52 ppm as compared to about 1800 ppm of sulfur oxides in typical exhaust flue gasstreams. For this, lab scale experiments were performed with a selected group of ILs tounderstand the absorption-desorption capacity of one such ionic liquids. One IL, named IL-A,was selected for it better performance and was further studied to better understand the reactionmechanism between the IL and SO2. Results were quite promising with good amount of SO2absorption and partial regenerative desorption of the solvent mixture.Based on the results, it was evident that the viscosity of the IL-A increased tremendously dueto SO2 dissolution, which necessitated the use of an additive (additive B) as a diluent. Thedilution effect on vapor-liquid-equilibrium (VLE) and other physical properties wereexperimentally analyzed. TGA and FTIR gave some insights to quantify the amount of solventloss during the recycling process and to learn about thermal properties and the temperatureoperating range for the absorption-desorption in order to maximize the efficiency.A mathematical scale-up design model of the absorber to support an actual 20 MW marinevessel combustion engine emitting 61.6 x106 L/hour of flue gas was developed in MATLAB.Theoretical modelling of the process helped in selecting the ideal packing material and tocompare the designed tower with traditional scrubber. For the same scrubber diameter, thedesigned tower height is about 3 meters higher; however, to reduce the footprint to half, anincrease of 4.6 meters in height is required. Other advantages include lower operating costs,lower solvent requirement and low storage for solvent and waste generation.