Binuclear Non-heme Iron Catalysts.

Caradonna, J. P.

Technical Information Center Oak Ridge Tennessee

关键词: Iron complexes;    Catalysts;    Methane;    Oxygenases;    Alkanes;   

RP-ID  :  DE2005832718

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

This project involved the investigation of the ability of non-heme iron metalloenzyme reactivity model complexes to catalyze the oxidation of alkane and arene molecules. The objectives were to synthesize a series of non-heme mononuclear and dinuclear iron complexes, characterize their electronic structure and reactivity properties, characterize intermediates formed during oxygen atom transfer chemistry, and elucidate the mechanisms and specificity of the reactions. These data also were to be compared to analogous heme-based chemistry.