High Efficiency Desulfurization of Synthesis Gas. Final Report, September 2002-March 2004.

Yi, K. B. ; Mukherjee, A. ; Podlaha, E. J. ; Harrison, D. P.

Technical Information Center Oak Ridge Tennessee

关键词: Synthesis gas;    Desulfurization;    Hydrogen sulfides;    Catalysts;    Electrochemisty;   

RP-ID  :  DE2004833407

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

Mixed metal oxides containing ceria and zirconia have been studied as high temperature desulfurization sorbents with the objective of achieving the DOE Vision 21 target of 1 ppmv or less H(sub 2)S in the product gas. The research was justified by recent results in this laboratory that showed that reduced CeO(sub 2), designated CeOn (1.5 < n < 2.0), is capable of achieving the 1 ppmv target in highly reducing gas atmospheres. The addition of ZrO(sub 2) has improved the performance of oxidation catalysts and three-way automotive catalysts containing CeO(sub 2), and was postulated to have similar beneficial effects on CeO(sub 2) desulfurization sorbents.