Thermodynamic Analysis of Thermophotovoltaic Efficiency and Power Density Tradeoffs.

Baldasara, P. F. ; Reynolds, J. E. ; Charache, G. W. ; DePoy, D. M. ; Ballinger, C. T. ; Donovan, T. ; Borrego, J. M.

Technical Information Center Oak Ridge Tennessee

关键词: Thermodynamic analysis;    Efficiency;    Energy conversion;    Performance;    Physics;   

RP-ID  :  DE2004821296

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

This report presents an assessment of the efficiency and power density limitations of thermophotovoltaic (TPV) energy conversion systems for both ideal (radiative-limited) and practical (defect-limited) systems. Thermodynamics is integrated into the unique process physics of TPV conversion, and used to define the intrinsic tradeoff between power density and efficiency. The results of the analysis reveal that the selection of diode bandgap sets a limit on achievable efficiency well below the traditional Carnot level. In addition it is shown that filter performance dominates diode performance in any practical TPV system and determines the optimum bandgap for a given radiator temperature. It is demonstrated that for a given radiator temperature, lower bandgap diodes enable both higher efficiency and power density when spectral control limitations are included. The goal of this work is to provide a better understanding of the basic system limitations that will enable successful long-term development of TPV energy conversion technology.