Vibrational Spectroscopy at High Pressures in CF(4): Implications to the Phase Diagram.

Lorenzana, H. E. ; Lipp, M. J. ; Evans, W. J. ; Hemmi, N.

Technical Information Center Oak Ridge Tennessee

关键词: Vibrational spectra;    Carbon tetrafluoride;    Raman spectra;    Phase diagrams;    Phase transitions;   

RP-ID  :  DE200515013136

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

The molecular analogue of methane, CF4 is the most fundamental saturated perfluorocarbon, exhibiting complex optical behavior that is highly unusual for such a simple molecular system. We present Raman measurements in solid CF4 over a wide range in pressure from 1.6 to over 30 GPa at room temperature. The Raman spectra exhibit polarization-dependent intensity variations and history-dependent absence or presence of high pressure modes. Our results compellingly demonstrate that previously identified phase transitions in CF4 based on Raman signatures need to be reconsidered. Though our data suggest possible new high-pressure transitions, we do not identify new phases because of spectral complexity. Finally, we used the measured longitudinal and transverse optical mode splitting to estimate the dipole moment derivative at high pressures and find it close to that of gaseous CF4.