科技报告详细信息
Ceramic Waste Form Process at Idaho National Laboratory.
Priebe, S.
Technical Information Center Oak Ridge Tennessee
关键词: Spent fuels;    Disposition;    Ceramics;    Electrometallurgy;    High-level radioactive wastes;   
RP-ID  :  DE2007918171
学科分类:工程和技术(综合)
美国|英语
来源: National Technical Reports Library
PDF
【 摘 要 】
The treatment of spent nuclear fuel for disposition using an electrometallurgical technique results in two high-level waste forms: a ceramic waste form (CWF) and a metal waste form. Reactive metal fuel constituents, including all the transuranic metals and the majority of the fission products remain in the salt as chlorides and are processed into the CWF. The solidified salt is containerized and transferred to the CWF process where it is ground in an argon atmosphere. Zeolite 4A is ground and then dried in a mechanically-fluidized dryer. The salt and zeolite are mixed in a V-mixer and heated to 500DGC to occlude the salt into the structure of the zeolite. The salt-loaded zeolite is cooled, mixed with borosilicate glass frit, and transferred to a crucible, which is placed in a furnace and heated to 925DGC. During this process, known as pressureless consolidation, the zeolite is converted to the final sodalite form and the glass thoroughly encapsulates the sodalite, producing a dense, leach-resistant final waste form.
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