The rapid decontamination of accidental liquid wastes containing various radioactive nuclides is important from the standpoint of radiation exposure reduction and radiation protection. For this purpose, the development of multi-functional microcapsules with high uptake ability for different radioactive nuclides is required for this treatment. In order to remove radioactive nuclides from the waste solutions, a large number of selective inorganic ion-exchangers and extractants have been developed. Since most of these materials are very fine powder or oily, they have some difficulties in handling for the practical applications.