To reduce design risks for future magnetically shielded Hall thrusters, a test was performed on the HERMeS to obtain data for optimizing the effect of magnetic shielding. As a part of this test, laser-induced fluorescence velocimetry was used to characterize the variations in the ion acceleration with different magnetic configurations. Four magnetic configurations representing varying amounts of magnetic shielding between the high-energy discharge plasma and the discharge channel walls were tested. The ion velocity data points to the possibility that different plasma-wall interaction physics applies to a magnetically shielded thruster than a non-shielded thruster. The transition point is very prominent and can potentially be used to test whether a thruster is fully magnetically shielded.