For real-time conjunction assessment (CA) operations, computation of the Probability of Collision (P(sub c)) typically depends on the state vector, its covariance, and the combined hard body radius (HBR) of both the primary and secondary space-craft. However, most algorithmic approaches that compute the P(sub c) use generic conservatively valued HBRs that may tend to go beyond the physical limitations of both spacecraft, enough to drastically change the results of a conjunction assessment mitigation decision. On the other hand, if the attitude of the spacecraft is known and available, then a refined HBR can be obtained that could result in an improved and accurate numerically-computed P(sub c) value. The goal of this analysis is to demonstrate the various calculated P(sub c) values obtained based on a number of different HBR calculation techniques, oriented in the encounter or conjunction plane at the time of closest approach (TCA). Since in most conjunctions the secondary object is a debris object and thus orders of magnitude smaller than the primary, the greatest operational benefit is wrought by developing a better size estimate and representation for the primary object. We present an analysis that includes the attitude information of the primary object in the HBR calculation and assesses the resulting P(sub c) values for conjunction assessment decision making.