The first goal of PACE mission science is to open new vistas in aquatic bio geochemistry by measuring non-chlorophyll pigments, separate chlorophyll and colored dissolved organic matter (CDOM) and characterize phytoplankton taxonomy. PACE science will follow aquatic biochemistry into ecosystems in coastal regions, estuaries, tidal wetlands and lakes. PACE's second science goal is to extend aerosoland cloud data-records begun by the passive EOS-era instruments, as an aerosol- cloud-climate continuation mission. Besides PACE, NASA has no plans for multi-angle radiometry to continue the MISR record nor for multi-angle polarimetry to continue the PARASOL record. A multi-angle polarimeter on PACE will reduce risk towards meeting the first goal and enable the realization of the second.