Li-ion 18650 Thermal Runaway Particulate Analysis

Nemanick, E Joseph ; Quinzio, Michael V ; Joseph, Paul ; Yong, Kim ; Goeppinger, Aura ; Walker, Don

关键词: THERMAL ANALYSIS;    LITHIUM BATTERIES;    INTERNATIONAL SPACE STATION;   

RP-ID  :  JSC-E-DAA-TN55607

美国|英语

来源: NASA Technical Reports Server

【 摘 要 】

Three types of atmospheres were tested for their effects on the particulates generated in a lithium ion (Li-ion) battery thermal runaway. Normal laboratory air (Ambient), a mixture of 23.5% O2/76.5% N2 meant to simulate the atmosphere on the International Space Station (ISS), and Vacuum environments were tested. Samsung 26F 18650 cells were driven to thermal runaway using heater tape, and the resultant particulates were collected analyzed using SEM/EDX, FTIR, GCMS, as well as conductivity and magnetic probes. All three conditions generated dense black particulate films composed of very fine carbon and metal particles. These films, however, were not very conductive, though individual particulates would be, and the particles demonstrated weak paramagnetism. FTIR and GCMS identified a substantial amount of volatile components in the particulate films, both organic partial combustion products, but also electrolyte salt products.