Permanently shadowed craters at the lunar poles contain water, ~5 wt% according to LCROSS. Interest in water for ISRU applications. Desire to 'ground truth' water using surface prospecting; e.g. Resource Prospector (RP) & RESOLVE. How to access subsurface water resources and accurately measure quantity; Excavation operations and exposure to lunar environment may affect the results A series a ground based dirty thermal vacuum tests are being conducted to better understand the subsurface sampling operations: Sample removal and transfer, Volatiles loss during sampling operations, Concept of operations, Instrumentation. This presentation covers: The capabilities of the VF-13 Thermal Vacuum Chamber (Tvac). The Resource Prospector TVAC hardware. The summary and results of 5 years of RP volatiles tests; 43 viable samples