科技报告详细信息
Coordinated Analysis of Organic Matter in Primitive Meteorites
Nevill, N ; Clemett, S J ; Messenger, S ; Thomas-Keprta, K L
关键词: ORGANIC MATERIALS;    ISOTOPES;    METEORITES;    MURCHISON METEORITE;    NANOPARTICLES;    GLOBULES;    CARBONACEOUS CHONDRITES;    NITROGEN 15;    GEOCHEMISTRY;    X RAY SPECTROSCOPY;    MASS SPECTROSCOPY;    FLUORESCENCE;    SCANNING ELECTRON MICROSCOPY;   
RP-ID  :  LPI Contrib. No. 2083,JSC-E-DAA-TN55978
学科分类:天文学(综合)
美国|英语
来源: NASA Technical Reports Server
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【 摘 要 】

Carbonaceous chondrites (CC) preserve a diverse range of organic matter formed within cold interstellar environments, the solar nebula, and during subsequent parent body asteroidal processing. This organic matter maintains a unique geochemical and istopic record of organic evolution [1-4]. Bulk studies of organics within CC have revealed a complex array of organic species. However, bulk studies invariably involve solvent extraction, resulting in a loss of spatial context of the host mineral matrix [3, 5]. Correlated in situ chemical and isotopic studies suggest preservation of interstellar organics in the form of spherical, often hollow, micrometer sized organic nano-globules. Nanoglobules often exhibit significant delta 15N and delta D enrichments that imply formation through fractionation of ion-molecule reactions within cold molecular clouds and/or the outer protoplanetary disk [5]. In situ studies such as 6-8 are necessary to understand the organic evolutionary stages of nanoglobules and other components in the nebula and parent body [7]. We carried out coordinated in situ micrometer-scale chemical, mineralogical and isotopic studies of the Murchison (CM2), QUE 99177 (CR3), and Tagish Lake (C2 Ung) CC. These studies were performed using fluorescent microscopy, two-step laser mass spectrometry (microL2MS), NanoSIMS, and Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray Spectroscopy (EDX). Comparative analysis of three different meteorites will help reveal the effects of parent body processes on the chemistry and isotopic composition of organic matter.

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