Amorphous Phase Characterization Through X-Ray Diffraction Profile Modeling: Implications for Amorphous Phases in Gale Crater Rocks and Soils

Achilles, C N ; Downs, G W ; Downs, R T ; Morris, R V ; Rampe, E B ; Ming, D W ; Chipera, S J ; Blake, D F ; Vaniman, D T ; Bristow, T F(NASA Ames Research Center, Moffett Field, CA, United States)

关键词: AMORPHOUS MATERIALS;    CRYSTALLINITY;    X RAY DIFFRACTION;    MARS (PLANET);    MARS CRATERS;    X RAY SPECTROMETERS;    ENVIRONMENT MODELS;    MARS SURFACE SAMPLES;    CURIOSITY ROVER;    SOIL SAMPLING;    SULFATES;    X RAYS;    ROCKS;    CHARACTERIZATION;    SCATTERING;   

RP-ID  :  JSC-E-DAA-TN53573,LPI Contrib. No. 2083

学科分类：天文学(综合)

美国|英语

来源: NASA Technical Reports Server

【 摘 要 】

The CheMin X-ray diffraction instrument on the Mars Science Laboratory rover has analyzed 18 rock and soil samples in Gale crater. Diffraction data allow for the identification of major crystalline phases based on the positions and intensities of well-defined peaks and also provides information regarding amorphous and poorly-ordered materials based on the shape and positions of broad scattering humps. The combination of diffraction data, elemental chemistry from APXS (Alpha Particle X-ray Spectrometer) and evolved gas analyses (EGA) from SAM (Sample Analysis at Mars) help constrain possible amorphous materials present in each sample (e.g., glass, opal, iron oxides, sulfates) but are model dependent. We present a novel method to characterize amorphous material in diffraction data and, through this approach, aim to characterize the phases collectively producing the amorphous profiles in CheMin diffraction data. This method may be applied to any diffraction data from samples containing X-ray amorphous materials, not just CheMin datasets, but we re-strict our discussion to Martian-relevant amorphous phases and diffraction data measured by CheMin or CheMin-like instruments.