Uranium for hydrogen storage applications : a materials science perspective.

Shugard, Andrew D. ; Tewell, Craig R. ; Cowgill, Donald F. ; Kolasinski, Robert D.

Sandia National Laboratories

关键词: Desorption;    Storage;    Hydrides;    08 Hydrogen;    Tritium;   

DOI  :  10.2172/993617
RP-ID  :  SAND2010-5195
RP-ID  :  AC04-94AL85000
RP-ID  :  993617

美国|英语

来源: UNT Digital Library

【 摘 要 】

Under appropriate conditions, uranium will form a hydride phase when exposed to molecular hydrogen. This makes it quite valuable for a variety of applications within the nuclear industry, particularly as a storage medium for tritium. However, some aspects of the U+H system have been characterized much less extensively than other common metal hydrides (particularly Pd+H), likely due to radiological concerns associated with handling. To assess the present understanding, we review the existing literature database for the uranium hydride system in this report and identify gaps in the existing knowledge. Four major areas are emphasized: {sup 3}He release from uranium tritides, the effects of surface contamination on H uptake, the kinetics of the hydride phase formation, and the thermal desorption properties. Our review of these areas is then used to outline potential avenues of future research.