Development of Pd-Ag Compostie Membrane for Separation of Hydrogen at Elevated Temperature

Ilias, Shamsuddin

North Carolina Agricultural & Technical State University

关键词: 10 Synthetic Fuels;    Supports;    Membranes;    Uses;    Temperature Range 0400-1000 K;   

DOI  :  10.2172/983650
RP-ID  :  None
RP-ID  :  FG26-05NT42492
RP-ID  :  983650

美国|英语

来源: UNT Digital Library

【 摘 要 】

Pd-based membrane reactor offers the possibility of combining reaction and separation in a single operation at high temperatures to overcome the equilibrium limitations experienced in conventional reactor configurations. In this project to develop a defect-free and hermally-stable Pd-film on microporous stainless steel (MPSS) support for H2-separation and membrane reactor applications, the electroless plating process was revisited with an aim to improve the membrane morphology. Specifically, this study includes; (a) an improvement f activation step using Pulse Laser Deposition (PLD), (b) development of a novel surfactant induced electroless plating (SIEP) for depositing robust Pd-film on microporous support, and (c) application of Pd-membrane as membrane reactor in steam methanol reforming (SMR) reactions.