Results for the First Quarter 2010 Tank 50 Wac Slurry Sample: Chemical and Radionuclide Contaminant Results

Reigel, M. ; Bibler, N.

Savannah River Site (S.C.)

关键词: Low-Level Radioactive Wastes;    Radioactive Waste Processing;    Liquid Wastes;    Chemical Composition;    Sampling;   

DOI  :  10.2172/982994
RP-ID  :  SRNL-STI-2010-00210
RP-ID  :  DE-AC09-08SR22470
RP-ID  :  982994

美国|英语

来源: UNT Digital Library

【 摘 要 】

This report details the chemical and radionuclide contaminant results for the characterization of the 2010 First Quarter sampling of Tank 50 for the Saltstone Waste Acceptance Criteria (WAC). Information from this characterization will be used by Liquid Waste Operations (LWO) to support the transfer of low-level aqueous waste from Tank 50 to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50 Waste Characterization System. The following conclusions are drawn from the analytical results provided in this report: (1) The concentrations of the reported chemical and radioactive contaminants were less than their respective WAC targets or limits unless noted in this section. (2) The reported detection limit for Isopar L is greater than the limit from Table 3 of the WAC. (3) The reported detection limits for {sup 59}Ni and {sup 94}Nb are above the requested limits from Reference 4. However, they are each below the limits established in Reference 6. (4) The reported detection limit for isopropanol is greater than the requested limit from Table 4 of the WAC. (5) The reported detection limits for 247Cm and 249Cf are above the requested limits from Reference 4. However, they are below the limits established in Reference 6. (6) Isopar L and Norpar 13 have limited solubility in aqueous solutions making it difficult to obtain consistent and reliable sub-samples. The values reported in this memo are the concentrations in the sub-sample as detected by the GC/MS; however, the results may not accurately represent the concentrations of the analytes in Tank 50.