Activated Carbon Composites for Air Separation

Contescu, Cristian I ; Baker, Frederick S ; Tsouris, Costas ; McFarlane, Joanna

Oak Ridge National Laboratory

关键词: Gas Chromatography;    Flow Rate;    Activated Carbon;    Air;    36 Materials Science;   

DOI  :  10.2172/969950
RP-ID  :  ORNL/TM-2007/239
RP-ID  :  DE-AC05-00OR22725
RP-ID  :  969950

美国|英语

来源: UNT Digital Library

【 摘 要 】

In continuation of the development of composite materials for air separation based on molecular sieving properties and magnetic fields effects, several molecular sieve materials were tested in a flow system, and the effects of temperature, flow conditions, and magnetic fields were investigated. New carbon materials adsorbents, with and without pre-loaded super-paramagnetic nanoparticles of Fe3O4 were synthesized; all materials were packed in chromatographic type columns which were placed between the poles of a high intensity, water-cooled, magnet (1.5 Tesla). In order to verify the existence of magnetodesorption effect, separation tests were conducted by injecting controlled volumes of air in a flow of inert gas, while the magnetic field was switched on and off. Gas composition downstream the column was analyzed by gas chromatography and by mass spectrometry. Under the conditions employed, the tests confirmed that N2 - O2 separation occurred at various degrees, depending on material's intrinsic properties, temperature and flow rate. The effect of magnetic fields, reported previously for static conditions, was not confirmed in the flow system. The best separation was obtained for zeolite 13X at sub-ambient temperatures. Future directions for the project include evaluation of a combined system, comprising carbon and zeolite molecular sieves, and testing the effect of stronger magnetic fields produced by cryogenic magnets.