Sulfur Partitioning During Vitrification of INEEL Sodium Bearing Waste: Status Report

Darab, John G. ; Graham, Dennis D. ; Macisaac, Brett D. ; Russell, Renee L. ; Smith, Harry D. ; Vienna, John D. ; Peeler, David K.

Pacific Northwest National Laboratory (U.S.)

关键词: Waste Glass;    Sulfate;    Partioning;    Ineel;    Sbw;   

DOI  :  10.2172/965662
RP-ID  :  PNNL-13588
RP-ID  :  AC05-76RL01830
RP-ID  :  965662

美国|英语

来源: UNT Digital Library

【 摘 要 】

The sodium bearing tank waste (SBW) at Idaho National Engineering and Environmental Laboratory (INEEL) contains high concentrations of sulfur (roughly 5 mass% of SO3 on a nonvolatile oxide basis). The amount of sulfur that can be feed to the melter will ultimately determine the loading of SBW in glass produced by the baseline (low-temperature, joule-heated, liquid-fed, ceramic-lined) melter. The amount of sulfur which can be fed to the melter is determined by several major factors including: the tolerance of the melter for an immiscible salt layer accumulation, the solubility of sulfur in the glass melt, the fraction of sulfur removed to the off-gas, and the incorporation of sulfur into the glass up to it?s solubility limit. This report summarizes the current status of testing aimed at determining the impacts of key chemical and physical parameters on the partitioning of sulfur between the glass, a molten salt, and the off-gas.