Critical Causes of Degradation in Integrated Laboratory Scale Cells during High Temperature Electrolysis

Sohal, M.S. ; O' ; Brien, J.E. ; Stoots, C.M. ; Hartvigsen, J. J. ; Larsen, D. ; Elangovan, S. ; Herring, J.S. ; Carter, J.D. ; Sharma, V.I. ; Yildiz, B.

Idaho National Laboratory

关键词: Solid Oxide Electrolysis Cell;    Testing;    Electrolysis;    Electrodes;    Oxides;   

DOI  :  10.2172/961923
RP-ID  :  INL/EXT-09-16004
RP-ID  :  DE-AC07-99ID-13727
RP-ID  :  961923

美国|英语

来源: UNT Digital Library

【 摘 要 】

An ongoing project at Idaho National Laboratory involves generating hydrogen from steam using solid oxide electrolysis cells (SOEC). This report describes background information about SOECs, the Integrated Laboratory Scale (ILS) testing of solid-oxide electrolysis stacks, ILS performance degradation, and post-test examination of SOECs by various researchers. The ILS test was a 720- cell, three-module test comprised of 12 stacks of 60 cells each. A peak H2 production rate of 5.7 Nm3/hr was achieved. Initially, the module area-specific resistance ranged from 1.25 Ocm2 to just over 2 Ocm2. Total H2 production rate decreased from 5.7 Nm3/hr to a steady state value of 0.7 Nm3/hr. The decrease was primarily due to cell degradation. Post test examination by Ceramatec showed that the hydrogen electrode appeared to be in good condition. The oxygen evolution electrode does show delamination in operation and an apparent foreign layer deposited at the electrolyte interface. Post test examination by Argonne National Laboratory showed that the O2-electrode delaminated from the electrolyte near the edge. One possible reason for this delamination is excessive pressure buildup with high O2 flow in the over-sintered region. According to post test examination at the Massachusetts Institute of Technology, the electrochemical reactions have been recognized as one of the prevalent causes of their degradation. Specifically, two important degradation mechanisms were examined: (1) transport of Crcontaining species from steel interconnects into the oxygen electrode and LSC bond layers in SOECs, and (2) cation segregation and phase separation in the bond layer. INL conducted a workshop October 27, 2008 to discuss possible causes of degradation in a SOEC stack. Generally, it was agreed that the following are major degradation issues relating to SOECs: • Delamination of the O2-electrode and bond layer on the steam/O2-electrode side • Contaminants (Ni, Cr, Si, etc.) on reaction sites (triple phase boundary) • Loss of electrical/ionic conductivity of electrolyte.