TRITIUM BARRIER MATERIALS AND SEPARATION SYSTEMS FOR THE NGNP

Sherman, S ; Thad Adams, T

Savannah River Site (S.C.)

关键词: Hydrogen Production;    Molecular Sieves;    Getters;    Hydrides;    08 Hydrogen;   

DOI  :  10.2172/935438
RP-ID  :  WSRC-STI-2008-00358
RP-ID  :  DE-AC09-96SR18500
RP-ID  :  935438

美国|英语

来源: UNT Digital Library

【 摘 要 】

Contamination of downstream hydrogen production plants or other users of high-temperature heat is a concern of the Next Generation Nuclear Plant (NGNP) Project. Due to the high operating temperatures of the NGNP (850-900 C outlet temperature), tritium produced in the nuclear reactor can permeate through heat exchangers to reach the hydrogen production plant, where it can become incorporated into process chemicals or the hydrogen product. The concentration limit for tritium in the hydrogen product has not been established, but it is expected that any future limit on tritium concentration will be no higher than the air and water effluent limits established by the NRC and the EPA. A literature survey of tritium permeation barriers, capture systems, and mitigation measures is presented and technologies are identified that may reduce the movement of tritium to the downstream plant. Among tritium permeation barriers, oxide layers produced in-situ may provide the most suitable barriers, though it may be possible to use aluminized surfaces also. For tritium capture systems, the use of getters is recommended, and high-temperature hydride forming materials such as Ti, Zr, and Y are suggested. Tritium may also be converted to HTO in order to capture it on molecular sieves or getter materials. Counter-flow of hydrogen may reduce the flux of tritium through heat exchangers. Recommendations for research and development work are provided.