Performance testing of aged hydrogen getters against criteria for interim safe storage of plutonium bearing materials.

Shepodd, Timothy J. ; Nissen, April ; Buffleben, George M.

Sandia National Laboratories

关键词: Flammability;    Removal;    Aging;    Storage;    Getters;   

DOI  :  10.2172/901710
RP-ID  :  SAND2007-0095
RP-ID  :  AC04-94AL85000
RP-ID  :  901710

美国|英语

来源: UNT Digital Library

【 摘 要 】

Hydrogen getters were tested for use in storage of plutonium-bearing materials in accordance with DOE's Criteria for Interim Safe Storage of Plutonium Bearing Materials. The hydrogen getter HITOP was aged for 3 months at 70 C and tested under both recombination and hydrogenation conditions at 20 and 70 C; partially saturated and irradiated aged getter samples were also tested. The recombination reaction was found to be very fast and well above the required rate of 45 std. cc H2h. The gettering reaction, which is planned as the backup reaction in this deployment, is slower and may not meet the requirements alone. Pressure drop measurements and {sup 1}H NMR analyses support these conclusions. Although the experimental conditions do not exactly replicate the deployment conditions, the results of our conservative experiments are clear: the aged getter shows sufficient reactivity to maintain hydrogen concentrations below the flammability limit, between the minimum and maximum deployment temperatures, for three months. The flammability risk is further reduced by the removal of oxygen through the recombination reaction. Neither radiation exposure nor thermal aging sufficiently degrades the getter to be a concern. Future testing to evaluate performance for longer aging periods is in progress.