Thermodynamic Factors Affecting UC1-xNxIrradiation and Synthesis | |
Lindemer, T.B. | |
Oak Ridge National Laboratory | |
关键词: Uranium Nitrides; Irradiation; Synthesis; Kernels; Thermodynamics; | |
DOI : 10.2172/885978 RP-ID : ORNL/TM-2004/158 RP-ID : DE-AC05-00OR22725 RP-ID : 885978 |
|
美国|英语 | |
来源: UNT Digital Library | |
【 摘 要 】
There is interest in attempting to synthesize nearly pure uranium nitride (UN) kernels for high-temperature gas-cooled reactor (HTGR) fuel. Because the proposed process involves carbothermic conversion of a urania-carbon mixture in nitrogen and because there is a complete ideal solution of uranium carbide (UC) and UN, which is written as UC{sub 1-x}N{sub x}, the practical value of x for fuel irradiation needs to be determined. Insight is to be gained by relevant thermodynamic calculations of carbide-nitride equilibria for the fuel and fission product systems. The equilibria are readily compared on the nitrogen-based Ellingham diagram, which, in turn, provides guidance in interpreting past irradiations and in synthesis of the UC{sub 1-x}N{sub x} kernels.
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
885978.pdf | 126KB | download |