Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone

Saiers, James ; Ryan, Joseph

University of Colorado Boulder

关键词: Surface Waters;    Radionuclide;    Filtration;    Colloid;    Strontium;   

DOI  :  10.2172/885273
RP-ID  :  DOE/ER/63491-3
RP-ID  :  FG07-02ER63491
RP-ID  :  885273

美国|英语

来源: UNT Digital Library

【 摘 要 】

Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloidassociated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.