EOS7C Version 1.0: TOUGH2 Module for Carbon Dioxide or Nitrogen inNatural Gas (Methane) Reservoirs

Oldenburg, Curtis M. ; Moridis,George J. ; Spycher, Nicholas ; Pruess, Karsten

Lawrence Berkeley National Laboratory

关键词: Natural Gas;    Diffusion;    Carbon Dioxide;    Nitrogen;    58 Geosciences;   

DOI  :  10.2172/878525
RP-ID  :  LBNL--56589
RP-ID  :  DE-AC02-05CH11231
RP-ID  :  878525

美国|英语

来源: UNT Digital Library

【 摘 要 】

EOS7C is a TOUGH2 module for multicomponent gas mixtures in the systems methane carbon dioxide (CH4-CO2) or methane-nitrogen (CH4-N2) with or without an aqueous phase and H2O vapor. EOS7C uses a cubic equation of state and an accurate solubility formulation along with a multiphase Darcy s Law to model flow and transport of gas and aqueous phase mixtures over a wide range of pressures and temperatures appropriate to subsurface geologic carbon sequestration sites and natural gas reservoirs. EOS7C models supercritical CO2 and subcritical CO2 as a non-condensible gas, hence EOS7C does not model the transition to liquid or solid CO2 conditions. The components modeled in EOS7C are water, brine, non-condensible gas, gas tracer, methane, and optional heat. The non-condensible gas (NCG) can be selected by the user to be CO2 or N2. The real gas properties module has options for Peng-Robinson, Redlich-Kwong, or Soave-Redlich-Kwong equations of state to calculate gas mixture density, enthalpy departure, and viscosity. Partitioning of the NCG and CH4 between the aqueous and gas phases is calculated using a very accurate chemical equilibrium approach. Transport of the gaseous and dissolved components is by advection and Fickian molecular diffusion. We present instructions for use and example problems to demonstrate the accuracy and practical application of EOS7C.