The Supramolecular Chemistry of Selective Anion Recognition for Anions of Environmental Relevance

Sessler, Jonathan L.

University of Texas at Austin

关键词: Chemistry;    37 Inorganic, Organic, Physical And Analytical Chemistry;    Sulfates;    54 Environmental Sciences;    Anions;   

DOI  :  10.2172/850321
RP-ID  :  EMSP-90301--2004a
RP-ID  :  FG02-04ER63741
RP-ID  :  850321

美国|英语

来源: UNT Digital Library

【 摘 要 】

In this first year of funding, progress has been made towards the stated project goal of generating useful sulfate extractants. A new series of bispyrrole-pyridine sulfate anion receptors was discovered and found to show very high sulfate-to-nitrate selectivity, a key prerequisite to generating a useful extractant. Progress was made towards developing the synthetic methodology needed to solubilize this system and other known receptors prepared by project collaborator, Prof. Kristin Bowman-James.