Fundamentals of Mercury Oxidation in Flue Gas

Lighty, JoAnn S. ; Silcox, Geoffrey ; Fry, Andrew ; Senior, Constance ; Helble, Joseph

University of Utah

关键词: 01 Coal, Lignite, And Peat;    Oxidation;    Kinetics;    Simulation;    Mercury;   

DOI  :  10.2172/837644
RP-ID  :  NONE
RP-ID  :  FG26-03NT41797
RP-ID  :  837644

美国|英语

来源: UNT Digital Library

【 摘 要 】

The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves two experimental scales and a modeling effort. The team is comprised of University of Utah, Reaction Engineering International, and University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studies include HCl, NOx, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 1 results for the experimental and modeling tasks. Experiments in the drop tube are just beginning and a new, speciated mercury analyzer is up and running. A preliminary assessment has been made for the drop tube experiments using the existing model of gas-phase kinetics.