Identification of Non-Pertechnetate Species In Hanford Tank Waste, Their Synthesis, Characterization, And Fundamental Chemistry

Ashely, Kenneth R. ; Schroeder, Norman ; Olivares, Jose A. ; Scott, Brian

Texas A & M University

关键词: Chemical Properties;    Redox Reactions;    Synthesis;    Radioactive Wastes;    Electrophoresis;   

DOI  :  10.2172/835704
RP-ID  :  DOE/ER/63281
RP-ID  :  FG07-01ER63281
RP-ID  :  835704

美国|英语

来源: UNT Digital Library

【 摘 要 】

This proposal had three major goals: (1) develop capillary electrophoresis mass spectrometry as a characterization technique, (2) separate a non-pertechnetate fraction from a waste sample and identify the non-pertechnetate species in it by CEMS, and (3) synthesize and characterize bulk quantities of the identified non-pertechnetate species and study their ligand substitution and redox chemistry.