Development of Biodegradable Isosaccharinate-Containing Foams for Decontamination of Actinides: Thermodynamic and Kinetic Reactions Between Isosaccharinate and Actinides on Metal and Concrete Surfaces

Rai, Dhanpat ; Moore, Robert C. ; Linfeng, Rao ; Tucker, Mark D.

Pacific Northwest National Laboratory (U.S.)

关键词: Removal;    Thermodynamics;    Decontamination;    Actinides;    37 Inorganic, Organic, Physical And Analytical Chemistry;   

DOI  :  10.2172/835043
RP-ID  :  EMSP-82715-2003
RP-ID  :  835043

美国|英语

来源: UNT Digital Library

【 摘 要 】

Actinide contamination of steel and concrete surfaces is a major problem within the DOE complex. Almost all current decontamination technologies rely on removal of the contaminated surface layer by mechanical means or by chemical methods, using harsh chemicals. Some of the technologies are ineffective. Others are expensive, labor intensive, and hazardous to workers. Still others create secondary mixed wastes that are not environmentally acceptable. This project seeks fundamental information that will lead to the development of a new and more environmentally acceptable technology for decontamination of actinides, especially Pu, on steel and concrete surfaces. The key component of this technology is isosaccharinate (ISA), a degradation product of cellulose materials that is biodegradable. Isosaccharinate will be incorporated into foams/gels for safe and easy use in decontamination of actinides from steel, concrete, and other surfaces. Thermodynamic data are being developed on the interactions of ISA with actinides and competing metals [e.g., Fe(III) and Ca(II)] under a wide range of conditions relevant to decontamination of steel and concrete. The efficiency of the ISA containing foams/gels/solutions for decontamination is also being tested. This project builds on capabilities at three different national laboratories, and represents a joint effort between PNNL, LBNL, and SNL.