科技报告详细信息
Binuclear Non-heme Iron Catalysts | |
Caradonna, J. P. | |
Yale University (United States) | |
关键词: Electronic Structure; Iron Complexes; Oxidation; Catalytic Effects; 37 Inorganic, Organic, Physical And Analytical Chemistry; | |
DOI : 10.2172/832718 RP-ID : NONE RP-ID : FG02-92ER14279 RP-ID : 832718 |
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美国|英语 | |
来源: UNT Digital Library | |
【 摘 要 】
This project involved the investigation of the ability of non-heme iron metalloenzyme reactivity model complexes to catalyze the oxidation of alkane and arene molecules. The objectives were to synthesize a series of non-heme mononuclear and dinuclear iron complexes, characterize their electronic structure and reactivity properties, characterize intermediates formed during oxygen atom transfer chemistry, and elucidate the mechanisms and specificity of the reactions.
【 预 览 】
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832718.pdf | 2238KB | download |