Binuclear Non-heme Iron Catalysts

Caradonna, J. P.

Yale University (United States)

关键词: Electronic Structure;    Iron Complexes;    Oxidation;    Catalytic Effects;    37 Inorganic, Organic, Physical And Analytical Chemistry;   

DOI  :  10.2172/832718
RP-ID  :  NONE
RP-ID  :  FG02-92ER14279
RP-ID  :  832718

美国|英语

来源: UNT Digital Library

【 摘 要 】

This project involved the investigation of the ability of non-heme iron metalloenzyme reactivity model complexes to catalyze the oxidation of alkane and arene molecules. The objectives were to synthesize a series of non-heme mononuclear and dinuclear iron complexes, characterize their electronic structure and reactivity properties, characterize intermediates formed during oxygen atom transfer chemistry, and elucidate the mechanisms and specificity of the reactions.