SYNTHESIS AND CHARACTERIZATION OF CO-AND H{sub 2}S-TOLERANT ELECTROCATALYSTS FOR PEM FUEL CELL

Ilias, Shamsuddin

North Carolina Agricultural and Technical State University

关键词: Electrocatalysts;    Testing;    Proton Exchange Membrane Fuel Cells;    Anodes;    Fuel Gas;   

DOI  :  10.2172/825776
RP-ID  :  NONE
RP-ID  :  FG26-02NT41673
RP-ID  :  825776

美国|英语

来源: UNT Digital Library

【 摘 要 】

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period, we have obtained base-line performance data of commercially available Pt-catalyst in our modified PEMFC Testing set-up. Synthesis of Pt-based bimetallic and tri-metallic electrocatalysts is in progress.