Spectroelectrochemical Sensor for Technetium Applicable to the Vadose Zone

Heineman, William R. ; Seliskar, Carl J. ; Bryan, Samuel A. ; Hubler, Timothy L.

University of Cincinnati, Dept. of Chemistry, P.O. Box 210172, Cincinnati, OH 45221-0172 (United States)

关键词: Spectrometers Sensor;    Monitoring;    Spectroelectrochemistry;    Ground Water;    37 Inorganic, Organic, Physical And Analytical Chemistry;   

DOI  :  10.2172/811916
RP-ID  :  DOE-ER62311 (2003)
RP-ID  :  FG07-96ER62311
RP-ID  :  811916

美国|英语

来源: UNT Digital Library

【 摘 要 】

The general aim of this project is to continue the design and implementation of a new sensor technology that offers the unprecedented levels of specificity needed for analysis of the complex chemical mixtures found at DOE sites nationwide. The new sensor concept combines the elements of electrochemistry, spectroscopy and selective partitioning into a single device that provides three levels of selectivity. The specific goal of this project is the development of a sensor for technetium (Tc) that is applicable to characterizing and monitoring the Vadose Zone and associated subsurface water at the Hanford site. The first goal is a sensor that determines technetium in the chemical form pertechnetate (TcO{sub 4}{sup -}). This report summarizes work during 6/16/01-6/15/02 of a three-year project that began on 9/15/99. During this period our efforts have focused on four areas that are discussed in the following sections. Electrochemistry of pertechnetate (TcO{sub 4}{sup -}) at bare ITO and film-coated ITO electrodes; Enhancing sensitivity by increasing analyte absorptivity; Development and characterization of selective films; and Improved field portable spectroelectrochemical sensor.