Gas Generation during Sodium Permanganate Addition to HB-Line Phase II Filtrate Tank

Hill, B.C.

Savannah River Site (S.C.)

关键词: Radioactive Waste Processing;    Permanganates;    Gases;    Sodium Compounds;    Tanks;   

DOI  :  10.2172/804064
RP-ID  :  WSRC-TR-2002-00350
RP-ID  :  AC09-96SR18500
RP-ID  :  804064

美国|英语

来源: UNT Digital Library

【 摘 要 】

HB-Line Phase II process requires the addition of sodium permanganate followed by a sodium nitrite addition to prevent the precipitation of plutonium solids in a non-geometrically safe vessel. Previous experimental work has shown this method effective. Current concerns are related to the gas generated by the reaction. Potential difficulties include tank over-pressurization and tank overflow due to foaming or eructation. It is also necessary to verify that the quantity of permanganate specified by the facility is sufficient to reach the desired endpoint in a single addition.