CO2 SELECTIVE CERAMIC MEMBRANE FOR WATER-GAS SHIFT REACTION WITH CONCOMITANT FOR THE RECOVERY OF CO2

National Energy Technology Laboratory (U.S.)

关键词: Leaching;    Membranes;    Water Gas Processes;    08 Hydrogen;    01 Coal, Lignite, And Peat;   

DOI  :  10.2172/795766
RP-ID  :  FC26-00NT40922--09
RP-ID  :  FC26-00NT40922
RP-ID  :  795766

美国|英语

来源: UNT Digital Library

【 摘 要 】

The reversibility study using TGA/MS has been completed. Our result shows that the hydrotalcite material we proposed exhibits a high degree of CO{sub 2} reversibility. In addition, at higher temperatures (>200 C), insignificant adesorption of water was observed. Combining these results, we conclude that the hydrotalcite we choose is an ideal candidate material for high temperature gas separations requiring hydrothermal stability. We also have focused on the optimization of membrane synthesis. The gel formed after combining the reagents is an ideal precursor for deposition within the porous membrane based upon the Al/Mg ratio analysis and impurity leaching study. Finally, we experimentally verify the crystal growth temperature ranging from 100 to 150 C. The crystal growth is also highly dependent upon the time. Our study shows a general growth pattern from 0 to >4 hours. In the next quarter, we will utilize the information obtained here to initiate the optimization of membrane synthesis.