High Efficiency Steam Electrolyzer

Pham, A.Q.

Lawrence Livermore National Laboratory

关键词: 08 Hydrogen;    Natural Gas;    Cathodes;    Electrolysis;    Oxygen;   

DOI  :  10.2172/792600
RP-ID  :  UCRL-ID-138838
RP-ID  :  W-7405-Eng-48
RP-ID  :  792600

美国|英语

来源: UNT Digital Library

【 摘 要 】

A novel steam electrolyzer has been developed. In conventional electrolyzers, oxygen produced from electrolysis is usually released in the air stream. In their novel design, natural gas is used to replace air in order to reduce the chemical potential difference across the electrolyzer, thus minimizing the electrical consumption. The oxygen from the electrolysis is consumed in either a total oxidation or a partial oxidation reaction with natural gas. Experiments performed on single cells shown a voltage reduction as much as 1 V when compared to conventional electrolyzers. Using thin film materials and high performance cathode and anode, electrolysis could be done at temperatures as low as 700 C with electrolytic current as high as 1 A/cm{sup 2} at a voltage of 0.5 V only. The 700 C operating temperature is favorable to the total oxidation of natural gas while minimizing the need for steam that is otherwise necessary to avoid carbon deposition. A novel tubular electrolyzer stack has been developed. The system was designed to produce hydrogen at high pressures, taking advantage of the simplicity and high efficiency of the electrochemical compressors. A complete fabrication process was developed for making electrolyzer tubes with thin film coatings. A 100 W stack is being built.