A Simplified Methodology for Estimating the Pressure Buildup and Hydrogen Concentration Within a 2R/6M Container

SANCHEZ,LAWRENCE C. ; OTTINGER,CATHY A. ; POLANSKY,GARY F.

Sandia National Laboratories

关键词: Radiolysis;    08 Hydrogen;    Analytical Solution;    Buildup;    Plutonium Oxides;   

DOI  :  10.2172/791883
RP-ID  :  SAND2001-2348
RP-ID  :  AC04-94AL85000
RP-ID  :  791883

美国|英语

来源: UNT Digital Library

【 摘 要 】

A simplified and bounding methodology for analyzing the pressure buildup and hydrogen concentration within an unvented 2R container was developed (the 2R is a sealed container within a 6M package). The specific case studied was the gas buildup due to alpha radiolysis of water moisture sorbed on small quantities (less than 20 Ci per package) of plutonium oxide. Analytical solutions for gas pressure buildup and hydrogen concentration within the unvented 2R container were developed. Key results indicated that internal pressure buildup would not be significant for a wide range of conditions. Hydrogen concentrations should also be minimal but are difficult to quantify due to a large variation/uncertainty in model parameters. Additional assurance of non-flammability can be obtained by the use of an inert backfill gas in the 2R container.