Extinction Limits of Nonadiabatic, Catalyst-Assisted Flames in Stagnation-Point Flow

Margolis, Stephen B. ; Gardner, Timothy J.

Sandia National Laboratories

关键词: Stagnation Point;    Catalytic Combustors;    Flames;    37 Inorganic, Organic, Physical And Analytical Chemistry;    Catalysts;   

DOI  :  10.2172/781978
RP-ID  :  SAND2001-8172
RP-ID  :  AC04-94AL85000
RP-ID  :  781978

美国|英语

来源: UNT Digital Library

【 摘 要 】

An idealized geometry corresponding to a premixed flame in stagnation-point flow is used to investigate the effects of catalysis on extending the extinction limits of on adiabatic stretched flames. Specifically, a surface catalytic reaction is assumed to occur on the stagnation plane, thereby augmenting combustion in the bulk gas with a exothermic surface reaction characterized by a reduced activation energy. Assuming the activation energies remain large, an asymptotic analysis of the resulting flame structure yields a formula for the extinction limit as a function of various parameters. In particular, it is demonstrated that the presence of a surface catalyst can extend the burning regime, thus counterbalancing the effects of heat loss and flame stretch that tend to shrink it. The analysis is relevant to small-volume combustors, where the increased surface-to-volume ratio can lead to extinction of the nonadiabatic flame in the absence of a catalyst.