Permanganate Treatment of DNAPLs in Reactive Barriers and Source Zone Flooding Schemes - Final Report

Schwartz, F.W.

Ohio State Univ., Columbus, OH (United States)

关键词: Consumption Rates;    Permanganate;    Oxidation;    Kinetics;    Catalysts;   

DOI  :  10.2172/775438
RP-ID  :  DOE/ER/14735
RP-ID  :  FG07-96ER14735
RP-ID  :  775438

美国|英语

来源: UNT Digital Library

【 摘 要 】

This study provides a detailed process-level understanding of the oxidative destruction of the organic contaminant emphasizing on reaction pathways and kinetics. A remarkable rise in the MnO{sup {minus}} consumption rate with TCA and PCE mixtures proves that the phase transfer catalysts have the ability to increase oxidation rate of DNAPLs either in pure phase or mixtures and that there is significant potential for testing the catalyzed scheme under field conditions. Secondly, as an attempt to enhance the oxidation of DNAPL, we are trying to exploit cosolvency effects, utilizing various alcohol-water mixtures to increase DNAPL solubilization. Preliminary results of cosolvency experiments indicate the enhancement in the transfer of nonaqueous phase TCE to TBA-water solution and the rate of TCE degradation in aqueous phase.