TCLP Preparation and Analysis of K East Basin Composite Sludge Samples

Silvers, KL ; Wagner, JJ ; Steele, RT

Pacific Northwest National Laboratory (U.S.)

关键词: Sludges;    Fuel Storage Pools;    Sampling;    11 Nuclear Fuel Cycle And Fuel Materials;    Phosphors;   

DOI  :  10.2172/760083
RP-ID  :  PNNL-13280
RP-ID  :  AC06-76RL01830
RP-ID  :  760083

美国|英语

来源: UNT Digital Library

【 摘 要 】

Sludge samples from the Hanford K East Basin were analyzed by the Toxicity Characterization Leaching Procedure (TCLP) to assist in the appropriate Resource Conservation and Recovery Act (RCIL4) designation of this material. Sludge samples were collected by Fluor Hanford, Inc. using the consolidated sludge sampling system (system that allows collection of a single sample from multiple sample locations). These samples were shipped to the Postirradiation Testing Laboratory (PTL, 327 Building) and then transferred to the Pacific Northwest National Laboratory (PNNL) Radiochemical Processing Laboratory (RPL, 325 Building) for recovery and testing. Two sludge composites were prepared, using the consolidated sludge samples, to represent K East canister sludge (sample KC Can Comp) and K East floor sludge (sample KC Floor Comp). Each composite was extracted in duplicate and analyzed in duplicate following pre-approved(a) TCLP extraction and analyses procedures. In addition, these samples and duplicates were analyzed for total RCRA metals (via acid digestion preparation). The work was conducted in accordance with the requirements of the Hanford Analytical Quality Assurance Requirements Document (HASQARD). A PNNL Quality Assurance Program compliant with J HASQARD was implemented for this effort. The results from the TCLP analyses showed that all RCRA metal concentrations were less than the TCLP limits for both the canister and floor composite samples and their respective duplicates.