Evaluation and Testing of Noble Metals Surrogates

Sundaram, S. K. ; Macisaac, Brett D. ; Cooper, Alan R. ; Tschauner, Candice H. ; Holbrook, Jeremy J.

Pacific Northwest National Laboratory (U.S.)

关键词: Ruthenium Oxides;    Thermodynamics;    Radioactive Waste Processing;    Physical Properties;    Tungsten Oxides;   

DOI  :  10.2172/15010037
RP-ID  :  PNNL-13681
RP-ID  :  AC05-76RL01830
RP-ID  :  15010037

美国|英语

来源: UNT Digital Library

【 摘 要 】

This report summarizes the results of testing and evaluation of noble metal surrogates that will support testing of noble metals in melters. The candidate system, potential surrogates, model glass systems, and test conditions have been chosen based on the existing reported data in literature as well as expertise existing at various sites, thermodynamics, physical properties, and cost. The methodology involves testing interaction of RuO2 and WO3 and other surrogates in the test melt followed by characterization of the bulk glass and oxide-glass melt interfaces. The report explains different techniques used for studying settling, crystallization, rheology, and partitioning of noble metals or surrogates or spinel phases in the selected systems. The report presents and discusses how these results support the selection of the suitable surrogate for RuO2. Finally the report concludes with the best-suited surrogate (WO3) proposed and makes suitable recommendations for the follow up melter test activities.