Determination of Reactive Surface Area of Melt Glass

Bourcier,W. L. ; Roberts, S. ; Smith, D. K. ; Hulsey, S. ; Newton,L. ; Sawvel, A. ; Bruton, C. ; Papelis, C. ; Um, W. ; Russell, C. E. ; Chapman,J.

Lawrence Livermore National Laboratory

关键词: Sample Preparation;    Surface Area;    Ground Water;    Source Terms;    Hydraulics;   

DOI  :  10.2172/15005717
RP-ID  :  UCRL-ID-145181
RP-ID  :  W-7405-ENG-48
RP-ID  :  15005717

美国|英语

来源: UNT Digital Library

【 摘 要 】

A comprehensive investigation of natural and manmade silicate glasses, and nuclear melt glass was undertaken in order to derive an estimate of glass reactive surface area. Reactive surface area is needed to model release rates of radionuclides from nuclear melt glass in the subsurface. Because of the limited availability of nuclear melt glasses, natural volcanic glass samples were collected which had similar textures and compositions as those of melt glass. A flow-through reactor was used to measure the reactive surface area of the analog glasses in the presence of simplified NTS site ground waters. A measure of the physical surface area of these glasses was obtained using the BET gas-adsorption method. The studies on analog glasses were supplemented by measurement of the surface areas of pieces of actual melt glass using the BET method. The variability of the results reflect the sample preparation and measurement techniques used, as well as textural heterogeneity inherent to these samples. Based on measurements of analog and actual samples, it is recommended that the hydraulic source term calculations employ a range of 0.001 to 0.01 m{sup 2}/g for the reactive surface area of nuclear melt glass.