ADVANCED CEMENTS FOR GEOTHERMAL WELLS

SUGAMA,T.

关键词: ALUMINIUM;    BRINES;    CALCIUM SILICATES;    CEMENTING;    CEMENTS;    CORROSION;    DRILLING;    GEOTHERMAL ENERGY;    GEOTHERMAL WELLS;    HYDRATES;    PERFORMANCE;    PERMEABILITY;    SILICATES;    WATER;    WELL CASINGS;   

DOI  :  10.2172/909955
RP-ID  :  BNL--77901-2007-IR
PID  :  OSTI ID: 909955
Others  :  R&D Project: 05171
Others  :  Other: EB4005030
Others  :  TRN: US200723%%298

学科分类：再生能源与代替技术

美国|英语

来源: SciTech Connect

【 摘 要 】

Using the conventional well cements consisting of the calcium silicate hydrates (CaO-SiO{sub 2}-H{sub 2}O system) and calcium aluminum silicate hydrates (CaO-Al{sub 2}O{sub 3}-SiO{sub 2}-H{sub 2}O system) for the integrity of geothermal wells, the serious concern confronting the cementing industries was their poor performance in mechanically supporting the metallic well casing pipes and in mitigating the pipe's corrosion in very harsh geothermal reservoirs. These difficulties are particularly acute in two geological regions: One is the deep hot downhole area ({approx} 1700 m depth at temperatures of {approx} 320 C) that contains hyper saline water with high concentrations of CO{sub 2} (> 40,000 ppm) in conjunction with {approx} 100 ppm H{sub 2}S at a mild acid of pH {approx} 5.0; the other is the upper well region between the well's surface and {approx} 1000 m depth at temperatures up to 200 C. The specific environment of the latter region is characterized by highly concentrated H{sub 2}SO{sub 4} (pH < 1.5) brine containing at least 5000 ppm CO{sub 2}. When these conventional cements are emplaced in these harsh environments, their major shortcoming is their susceptibility to reactions with hot CO{sub 2} and H{sub 2}SO4, thereby causing their deterioration brought about by CO{sub 2}-catalyzed carbonation and acid-initiated erosion. Such degradation not only reduced rapidly the strength of cements, lowering the mechanical support of casing pipes, but also increased the extent of permeability of the brine through the cement layer, promoting the rate of the pipe's corrosion. Severely carbonated and acid eroded cements often impaired the integrity of a well in less than one year; in the worst cases, casings have collapsed within three months, leading to the need for costly and time-consuming repairs or redrilling operations. These were the reasons why the geothermal well drilling and cementing industries were concerned about using conventional well cements, and further their deterioration was a major impediment in expediting the development of geothermal energy resources.